orthonym.validation.spelling.checks_thioperoxol

Note

Internal API. Names and behaviour may change between releases.

Spelling checks of the thioperoxol names, read lexically (registered with orthonym.validation.pin_spelling.register()).

A twin read-back proves the structure of a thioperoxol name, never its spelling (validation.thioperoxol_twin): OPSIN reads ‘cyclohexane-1-sulfenic acid’ and ‘ethane-sulfenate’ for the structures of ‘cyclohexane-1-SO-thioperoxol’ and ‘ethane-SO-thioperoxolate’, neither of which is the PIN.

• (the Blue Book) “The locant ‘1’ is omitted:… (c) in monosubstituted homogeneous monocyclic rings” (:2913), ‘cyclohexanethiol (PIN)’: a ring with a thioperoxol suffix and nothing else cites no locant, ‘cyclohexane-SO-thioperoxol’.

• Anions derived from hydroxy compounds (:41011): ‘CH3-CH2-S-O- ethane(SO-thioperoxolate) (PIN)’ (:41035): the parent hydride that ends without a locant is followed by the enclosed suffix.

orthonym.validation.spelling.checks_thioperoxol.monocycle_locant_check(mol, name)

A monosubstituted monocycle whose thioperoxol suffix cites the locant 1 (c),:2913).

orthonym.validation.spelling.checks_thioperoxol.enclosed_anion_suffix_check(mol, name)

A thioperoxolate of a parent without a locant that does not enclose its suffix (:41035).